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1/ ENERGY BANDS IN SOLIDS
In this chapter we begin with a review of the basic atomic properties of
matter leading to discrete electronic energy levels in atoms. We find
that these energy levels are spread into energy bands in a crystal.
This band structure allows us to distinguish between an insulator, a
semiconductor, and a metal.
1-1
CHARGED PARTICLES
The charge, or quantity, of negative electricity and the mass of the
electron have been found to be 1.60 X 10- 19 C (coulomb) and
9.11 X 10- 31 kg, respectively. The values of many important physical
constants are given in Appendix A, and a list of conversion factors and
prefixes is given in Appendix B. Some idea of the number of electrons
per second that represents current of the usual order of magnitude is
readily possible. F'or example, since the charge per electron is
1.60 X 10- 19 C, the number of electrons per coulomb is the reciprocal
of this nutnber, or approximately, 6 X 10 18 Further, since a current
of 1 A (ampere) is the flow of 1 Cis, then a current of only 1 pA (1 picoampere, or 10- 12 A) represents the motion of approximately 6 million
electrons per second. Yet a current of 1 pA is so small that considerable
difficulty is experienced in attempting to measure it.
The charge of a positive ion is an integral multiple of the charge
of the electron, although it is of opposite sign. For the case of singly
ionized particles, the charge is equal to that of the electron. For the
case of doubly ionized particles, the ionic charge is twice that of the
electron.
The mass of an atom is expressed as a number that is based on the
choice of the atomic weight of oxygen equal to 16. The mass of a
hypothetical atom of atomic weight unity is, by this definition, onesixteenth that of the mass of monatomic oxygen and has been calculated to be 1.66 X 10- 27 kg. Hence, to calculate the mass in kilograms
1
2 / INTEGRATED ELECTRONICS
Sec. J-2
of any atom, it is necessary only to...